Imaginary Robots
My name is Jesse van Herk, and I make imaginary robots for a living. I am a software engineer with experience in e-commerce, social networking, and large-scale systems. This site documents my travels both online and across the globe - you can either browse this site directly or follow me on your favourite sites.
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You can install either KDE or XFCE environments easily from an existing ubuntu installation or from their liveCDs. I will assume you already have a working ubuntu install and want to switch desktops without reinstalling.
For a full KDE environment plus KDE applications, install the kubuntu-desktop meta-package from the main repositories. Kubuntu is focused on being "friendly", which might match up better with your usability needs. Their website is http://kubuntu.org.
For a full XCFE environment plus lightweight applications, install the xubuntu-desktop meta-package from the 'universe' repository. Xubuntu is focused on being fast - their website is http://xubuntu.org .
These are official ubuntu packages and use most of the same underlying systems and applications as the standard Ubuntu desktop. You can install these alternative desktops easily using your package manager/software center by looking for the appropriate package listed above. Note that kubuntu-desktop in particular will bring in many applications/libraries as dependencies, since it uses the KDE equivalents of a lot of Gnome software (Koffice rather than Evolution, Amarok rather than Banshee, etc).

Jesse van Herk